Gaskets for CO2 Electrolysers

Sealing a CO₂ electrolyzer presents unique challenges, especially when operating with Gas Diffusion Electrodes (GDEs). A proper seal must be achieved without crushing the porous GDE structure. Our GDE Sealing Gasket Package has been specifically engineered to address these challenges, enabling a “zero-gap” cell configuration to reduce ohmic losses and allow for higher current densities.

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GDE Sealing Gaskets for CO Electrolyzers

Precision Sealing for Gas Diffusion Electrodes in CO₂RR

Sealing a CO₂ electrolysis cell with a gas diffusion electrode is not the same problem as sealing a standard electrochemical flow cell. The GDE is a porous, delicate, gas-permeable structure; the seal has to isolate the gas side from the liquid side without collapsing the gas-transport pathways that make the GDE work. Our GDE Sealing Gasket Package is purpose-built for this: a thin adhesive Kapton edge-seal bonds directly to the GDE perimeter, while a separate frame gasket (PTFE, Viton, or EPDM) sets the compartment thickness and carries the structural compression. The result is a tight gas/liquid seal with the GDE’s active area completely intact.

Package Contents

The GDE Sealing Gasket Package contains two complementary components that work together.

  • GDE Frame Gasket — a flat ring gasket with a 3×3 cm or 6×6 cm cut-out that accepts the GDE and sets the compartment thickness. Available in PTFE, Viton (FKM), or EPDM. Six standard thicknesses: 0.05, 0.1, 0.25, 0.5, 1.0, and 2.0 mm. Each pack ships with 2 gaskets, so stacks can be built up to match any GDE thickness — only the gasket facing the liquid side receives the Kapton seal.
  • Adhesive Kapton Sealing Gasket — a polyimide edge-seal (25.4 µm Kapton + 38.1 µm silicone adhesive = 63.5 µm total) that bonds the GDE to the frame gasket and creates the gas-tight, liquid-tight interface. Supplied in packs of 10 per flow-field size, so multiple assemblies can be made from a single package.

Exact active-area control

The Kapton edge-seal does double duty: it seals the GDE perimeter and precisely defines the exposed electrochemical active area. A 3×3 cm GDE paired with the 2.5×2.5 cm Kapton template yields exactly 6.25 cm² of exposed active area; a 6×6 cm GDE with the 5×5 cm template yields exactly 25 cm². This matters for CO₂RR kinetic studies where current density calculations, Faradaic efficiency, and catalyst loading per square centimetre need to be repeatable across experiments and across labs.

Applications

The GDE Sealing Gasket Package is designed for the Redox-Flow 3- and 4-compartment cell and for any setup that needs a gas-tight, liquid-tight GDE seal. Typical applications include:

  • CO2 electrolysis
  • Oxygen Depolarized Cathode (ODC) studies, where O₂ is fed to a GDE cathode for depolarized chloralkali or similar processes
  • Other gas/liquid-interface electrochemistry where the GDE must stay intact while separating a gas stream from a liquid electrolyte

These gaskets are used in combination with our modular CO₂ electrolysis cells. For the underlying hardware, see CO₂ Electrolysis Cells — in particular the X-Cell 3/4-compartment for the 2.5×2.5 cm and 5×5 cm formats described here, and the M-Cell Full Cell Configuration I for 1 cm² three-compartment CO₂RR work with standard electrodes.

FAQ

Why do I need a special gasket for GDEs?

GDEs are porous and gas-permeable; a standard gasket carries compression across the full face and crushes the gas-diffusion pathways. A GDE-specific package separates the two jobs: a thin Kapton edge-seal (63.5 µm) bonds and seals the GDE perimeter, while a separate frame gasket carries the compartment’s structural compression. The GDE’s active face stays open and functional. Designed for zero-gap setups.

What GDE thicknesses does the package support?

The GDE Frame Gasket is supplied in 0.05, 0.1, 0.25, 0.5, 1.0, and 2.0 mm thicknesses, and frame gaskets can be stacked to match any GDE thickness. Only the gasket at the GDE’s liquid-side interface receives the Kapton seal, so stack height and sealing geometry stay independent. 

What GDE sizes does the package accept?

3×3 cm and 6×6 cm. With the matching Kapton adhesive gasket, the exposed active area becomes exactly 2.5×2.5 cm (6.25 cm²) or 5×5 cm (25 cm²) — matching the flow-field dimensions of our X-Cell family.

Which frame gasket material should I choose?

PTFE for the widest chemical compatibility (full Ph range, halogens, aggressive anolytes/catholytes). Viton (FKM) for most CO₂RR service with good compression set and resilience. EPDM for alkaline-only service where low cost matters. All three are stocked in all six standard thicknesses.

Does this gasket package enable zero-gap cell operation?

Yes. Our GDE gasket package has been specifically designed for getting a proper seal without crushing the porous GDE structure – enabling zero-gap cell configurations, reducing ohmic losses and allowing for higher current densities.

How many assemblies do I get from one package?

The Kapton adhesive gasket ships in packs of 10 per flow-field size, so a single order supports multiple cell rebuilds. Frame gaskets ship in packs of 2 at each thickness/material combination — order extras if you’re running long campaigns or trialling multiple GDE thicknesses.

Can the gaskets be reused?

The Kapton adhesive gasket is single-use — once bonded to a GDE it cannot be cleanly removed and re-applied. The frame gaskets (PTFE, Viton, EPDM) can be reused across assemblies if undamaged.

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